Synthesis and characterisation of a new chiral ruthenium picket-fence porphyrin and its use in chiral recognition of racemic isocyanides

Authors
Galardon, E Lukas, M Le Maux, P Simonneaux, G
Citation
E. Galardon et al., Synthesis and characterisation of a new chiral ruthenium picket-fence porphyrin and its use in chiral recognition of racemic isocyanides, TETRAHEDR L, 40(14), 1999, pp. 2753-2756
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
14
Year of publication
1999
Pages
2753 - 2756
Database
ISI
SICI code
0040-4039(19990402)40:14<2753:SACOAN>2.0.ZU;2-3
Abstract
The preparation of a new chiral porphyrin bearing eight optically active pi ckets, four on each side of the porphyrin plane is described. Chiral recogn ition in the complexation of racemic isocyanide to the ruthenium compound l eads to the formation of three stereoisomers with low stereoselectivity (15 %). (C) 1999 Elsevier Science Ltd. All rights reserved.