A reactive DC magnetron discharge produced in a TIN deposition system was i
nvestigated using optical emission spectroscopy. The influence of He, Ne an
d Kr addition into an Ar + N-2 working atmosphere was investigated. Additio
n of small percentages of He or Ne in the working atmosphere of Ar + N-2, c
aused a decrease of the N-2(+) (B)/N-2(C) ratio, whle with Kr addition the
ratio increased. The known decrease of the relative intensity of Ti lines f
or N-2 addition was also observed for He addition, while it increases when
Ne and Kr are added. XRD analysis of TiN thin films revealed that He additi
on determines the same effect as N-2. This behavior is explained by N and N
+ density increase for He addition. (C) 1999 Elsevier Science Ltd. All righ
ts reserved.