A TRINUCLEAR PALLADIUM(II) COMPLEX WITH BRIDGING 2-HYDROXYACETOPHENONE N-4-ETHYLTHIOSEMICARBAZONE LIGANDS - AN UNUSUAL DIMETHYLFORMAMIDE PROMOTED DEPROTONATION AND AGGREGATION

Authors
KOVALADEMERTZI D KOURKOUMELIS N WEST DX VALDESMARTINEZ J HERNANDEZORTEGA S
Citation
D. Kovalademertzi et al., A TRINUCLEAR PALLADIUM(II) COMPLEX WITH BRIDGING 2-HYDROXYACETOPHENONE N-4-ETHYLTHIOSEMICARBAZONE LIGANDS - AN UNUSUAL DIMETHYLFORMAMIDE PROMOTED DEPROTONATION AND AGGREGATION, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (6), 1998, pp. 861-863
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY → ACNP
ISSN journal
14341948
Issue
6
Year of publication
1998
Pages
861 - 863
Database
ISI
SICI code
1434-1948(1998):6<861:ATPCWB>2.0.ZU;2-L
Abstract
The X-ray crystal structure of a palladium(II) complex of 2-hydroxyace tophenone N-4-ethylthiosemicarbazone (H(2)Ap4E) shows it to be a trian gular, trinuclear complex with bridging thiosemicarbazonato sulfur ato ms. This species can be formed from a monomer on dissolution in DMF or directly from Li2PdCl4 and the thiosemicarbazone in methanol-ammonia solution.