REACTION OF ALKYNYL ALKOXY METAL (CR, W) CARBENE COMPLEXES WITH 1,3-DINITROGEN SYSTEMS - A DIRECT ENTRY TO THE PYRIMIDINE SKELETON

Authors
POLO R MORETO JM SCHICK U RICART S
Citation
R. Polo et al., REACTION OF ALKYNYL ALKOXY METAL (CR, W) CARBENE COMPLEXES WITH 1,3-DINITROGEN SYSTEMS - A DIRECT ENTRY TO THE PYRIMIDINE SKELETON, Organometallics, 17(11), 1998, pp. 2135-2137
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
11
Year of publication
1998
Pages
2135 - 2137
Database
ISI
SICI code
0276-7333(1998)17:11<2135:ROAAM(>2.0.ZU;2-1
Abstract
The reaction of alkynyl alkoxy metal (Cr, W) carbene complexes with 1, 3-dinitrogen systems (amidines, guanidines, ureas) is described. In al l cases, the main product obtained corresponds to the cycloadduct whos e cyclic structure may be related to a pyrimidinic ring arising from a formal [3 + 3] cycloaddition, between the metal carbene complexes and the dinitrogen systems.