Authors
Citation
Be. Eichler et al., SYNTHESIS AND STRUCTURE OF A 1-GERMAPROPADIENE, Organometallics, 17(11), 1998, pp. 2147-2148
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
ISSN journal
02767333
Volume
17
Issue
11
Year of publication
1998
Pages
2147 - 2148
Database
ISI
SICI code
0276-7333(1998)17:11<2147:SASOA1>2.0.ZU;2-K
Abstract
The reaction of t-BuLi with a fluoroalkynyl-germane produces the title
compound, 1. Single-crystal X-ray analysis shows the Ge=C bond length
to be 1.783(2) Angstrom. The Ge atom is somewhat pyramidalized, and t
he Ge=C=C bond angle (159.2 degrees) reveals a bent structure at the c
entral carbon atom.