LITHIUM PNICTIDOALUMINATES (ET2O)(2)LI[MU-E(SIME3)(2)](2)ALH2 (E = P,AS) - NEW MIXED-METAL PNICOGEN-BRIDGED 4-MEMBERED RING COMPOUNDS

Authors
JANIK JF WELLS RL WHITE PS
Citation
Jf. Janik et al., LITHIUM PNICTIDOALUMINATES (ET2O)(2)LI[MU-E(SIME3)(2)](2)ALH2 (E = P,AS) - NEW MIXED-METAL PNICOGEN-BRIDGED 4-MEMBERED RING COMPOUNDS, Organometallics, 17(11), 1998, pp. 2361-2365
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
11
Year of publication
1998
Pages
2361 - 2365
Database
ISI
SICI code
0276-7333(1998)17:11<2361:LP((=P>2.0.ZU;2-M
Abstract
The lithium pnictidoaluminates (Et2O)(2)Li[mu-E(SiMe3)(2)](2)AlH2, E = P (1) and As (2), were obtained from the reactions between LiAlH4 and E(SiMe3)(3) in diethyl ether by following dehydrosilylation chemistry described earlier by us for related gallium derivatives. No reaction was detected for E = N. Single-crystal X-ray diffraction studies for 1 and 2 provided the isomorphous structural solutions featuring the pla nar four-membered {Li[mu-E](2)Al} cores.