SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF A NEW MONONUCLEAR BENZYL-COBALT COMPLEX CONTAINING MIXED TRIDENTATE IMINO-OXIME AND DIAMINE LIGANDS

Authors
DREOS R HERLINGER E TAUZHER G VUANO S NARDIN G RANDACCIO L
Citation
R. Dreos et al., SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF A NEW MONONUCLEAR BENZYL-COBALT COMPLEX CONTAINING MIXED TRIDENTATE IMINO-OXIME AND DIAMINE LIGANDS, Organometallics, 17(11), 1998, pp. 2366-2369
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
11
Year of publication
1998
Pages
2366 - 2369
Database
ISI
SICI code
0276-7333(1998)17:11<2366:SCAROA>2.0.ZU;2-C
Abstract
The complex [C6H5CH2Co(L)(LR)]ClO4 (3), where L = 2-((2-pyridylethyl)i mino)-3-butanone oximato and LR = 2-((2-pyridylethyl)amino)-3-aminobut ane has been prepared by reduction, with NaBH4 of the complex [Co-III( L)(2)]ClO4, followed by addition of C6H5CH2Cl. The compounds was chara cterized in the solid state by X-ray analysis. The complex undergoes C o-C homolytic cleavage under acidic conditions, giving dibenzyl under a nitrogen atmosphere and benzaldehyde in the presence of air.