UATRIS(MU-OXYDIACETATO)EUROPIUM(III)LANTHANUM(III) PENTAHYDRATE

Authors
BAGGIO R GARLAND MT PEREC M
Citation
R. Baggio et al., UATRIS(MU-OXYDIACETATO)EUROPIUM(III)LANTHANUM(III) PENTAHYDRATE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 591-594
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
5
Pages
591 - 594
Database
ISI
SICI code
0108-2701(1998)54:<591:UP>2.0.ZU;2-D
Abstract
The new heterobimetallic complex [{LaEu(oda)(3)(H2O)(3).-5H(2)O}n] (od a = -O2CCH2OCH2CO2-) has been synthesized and structurally characteriz ed. Three tridentate oda ligands are coordinated to the smaller Eu-III cation, while six adjacent outer carboxylate O atoms and three metal- bound water O atoms are bonded to the larger La-III cation. The struct ure consists of a three-dimensional network with the metal centers bri dged by oda carboxylate groups, with Eu...La separations of 6.95 (1) A ngstrom.