NEW-TYPE OF HETEROGENEOUS LIQUID-PHASE CA TALYSTS FOR HYDROCARBONS AND THEIR DERIVATIVES - VANADIUM PHOSPHATES

Authors
ZAZHYGALOV VO GASIOR M VARTIKYAN L PODOBINSKI J BACHERYKOVA IV
Citation
Vo. Zazhygalov et al., NEW-TYPE OF HETEROGENEOUS LIQUID-PHASE CA TALYSTS FOR HYDROCARBONS AND THEIR DERIVATIVES - VANADIUM PHOSPHATES, Teoreticeskaa i eksperimental'naa himia, 34(1), 1998, pp. 43-46
Citations number
9
Categorie Soggetti
Chemistry Physical
Journal title
Teoreticeskaa i eksperimental'naa himia → ACNP
ISSN journal
04972627
Volume
34
Issue
1
Year of publication
1998
Pages
43 - 46
Database
ISI
SICI code
0497-2627(1998)34:1<43:NOHLCT>2.0.ZU;2-Z
Abstract
Activity of vanadium phosphates in the oxidation reactions of 10 hydro carbons and their derivatives (benzene, phenol, toluene, naphthalene, naphthol, alpha-, beta-, gamma-methylpyridine, pyridine, cyclohexanol) with hydrogen peroxide has been studied for the first time. It has be en established that catalytic activity and composition of the products depend on the nature of both vanadium phosphate phase and additives i ntroduced in it. It has been shown that together with typical products of liquid-phase oxidation the proposed catalysts permit to obtain som e new compounds.