RAYLEIGH-BENARD-MARANGONI INSTABILITIES DURING EVAPORATION OF AQUEOUSALCOHOL-SOLUTIONS, DETECTED BY PYROELECTRIC SENSORS

Citation
M. Chirtoc et al., RAYLEIGH-BENARD-MARANGONI INSTABILITIES DURING EVAPORATION OF AQUEOUSALCOHOL-SOLUTIONS, DETECTED BY PYROELECTRIC SENSORS, Instrumentation science & technology, 26(2-3), 1998, pp. 133-144
Citations number
10
Categorie Soggetti
Instument & Instrumentation","Chemistry Analytical
ISSN journal
10739149
Volume
26
Issue
2-3
Year of publication
1998
Pages
133 - 144
Database
ISI
SICI code
1073-9149(1998)26:2-3<133:RIDEOA>2.0.ZU;2-H
Abstract
A simple pyroelectric Sensor is presented for on-line monitoring of Ra yleigh-Benard-Marangoni convective instabilities in methanol, ethanol and isopropanol aqueous solutions, caused by alcohol evaporation from the free surface of the liquid. The signals measured at the liquid-sub strate interface represent thermal fluctuations of the order of 10(-2) K, having a frequency spectrum between 0.08 Hz and 0.4 Hz. The numeri cal estimation of the Rayleigh and Marangoni numbers leads to the conc lusion that the latter is dominant in the conditions of the experiment . The amplitude and duration of the thermal noise are investigated as a function of alcohol concentration. An attempt is made to determine c haracteristic invariant quantities.