ELECTRICAL-PROPERTIES AND SPECTROSCOPIC STUDIES OF HCLO4-DOPED POLY(P-DIETHYNYLBENZENE)

Authors
ZHAN XW YANG MJ WAN MX
Citation
Xw. Zhan et al., ELECTRICAL-PROPERTIES AND SPECTROSCOPIC STUDIES OF HCLO4-DOPED POLY(P-DIETHYNYLBENZENE), Synthetic metals, 94(3), 1998, pp. 249-253
Citations number
13
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
94
Issue
3
Year of publication
1998
Pages
249 - 253
Database
ISI
SICI code
0379-6779(1998)94:3<249:EASSOH>2.0.ZU;2-P
Abstract
Electrical properties of poly(p-diethynylbenzene) (PDEB), chemically d oped with perchloric acid (HClO4), were investigated as a function of dopant concentration and relative humidity. The doped polymer was char acterized by X-ray photoelectron spectroscopy (XPS), W-Vis, LR, electr on spin resonance (ESR) and scanning electron microscopy (SEM). A poss ible structure of the HClO4-doped PDEB was proposed on the basis of sp ectroscopic studies. In the presence of humidity, HClO4-doped PDEB fol lows the proton conduction mechanism. (C) 1998 Elsevier Science S.A. A ll rights reserved.