ELECTRONIC-STRUCTURE CLOSE TO E(F) IN LOW-LEVEL ALKALI-DOPED C-60

Citation
Sl. Molodtsov et al., ELECTRONIC-STRUCTURE CLOSE TO E(F) IN LOW-LEVEL ALKALI-DOPED C-60, Journal of physics. Condensed matter, 6(4), 1994, pp. 925-932
Citations number
29
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09538984
Volume
6
Issue
4
Year of publication
1994
Pages
925 - 932
Database
ISI
SICI code
0953-8984(1994)6:4<925:ECTEIL>2.0.ZU;2-6
Abstract
High-resolution photoemission study of the valence-band electronic str ucture of A(x)C(60) (A = K or Cs; x less than or similar to 3) close t o EF reveals a phase separation into components exhibiting a dilute so lid solution of alkali in fullerite (alpha-C-60) and A(3)C(60). The al pha-C-60 phase is found to be remarkably stable against oxidation. Our analysis shows a strongly correlated electronic system in this phase. The similarity of the present data to previously published results fo r Li-, Na- and Rb-doped C-60 demonstrates the common character of the observed phenomena for this series of alkali-doped fullerites.