THE KINETICS OF THE SN(II) SN ELECTRODE-REACTION IN PURE MOLTEN TIN DICHLORIDE/

Authors
KAZMIERCZAK J KOWALCZEWSKA K
Citation
J. Kazmierczak et K. Kowalczewska, THE KINETICS OF THE SN(II) SN ELECTRODE-REACTION IN PURE MOLTEN TIN DICHLORIDE/, Polish Journal of Chemistry, 72(6), 1998, pp. 1037-1044
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
72
Issue
6
Year of publication
1998
Pages
1037 - 1044
Database
ISI
SICI code
0137-5083(1998)72:6<1037:TKOTSS>2.0.ZU;2-M
Abstract
Results of electrochemical investigation of the Sn(II)/Sn electrode re action in pure molten tin(II) chloride are presented. The exchange cur rent density has been determined by relaxation and impedance methods a s 1.6 A cm(-2) for the anodic and 1.2 A cm(-2) for the cathodic proces s, both exhibiting a weak temperature dependence. Both, the inductive model of a double layer of a metallic electrode immersed in its pure m olten salt, and a barrierless electron transition have been confirmed.