The record-high thermal conductivity of high-quality diamond makes it
a natural choice for many applications in thermal management. The colu
mnar microstructure of chemical-vapor-deposited diamond thick films, h
owever, causes anisotropy and a strong gradient in the conductivity, b
oth of which can be understood in terms of phonon-scattering defects t
hat aggregate near grain boundaries. Techniques to take maximum advant
age of the high thermal conductivity include the removal of fine-grain
ed low-conductivity material near the substrate surface and the provis
ion of excellent thermal contact between the diamond and heat sources
or sinks.