THE UNPRECEDENTED TRANSFORMATION OF A STERICALLY CROWDED CYCLOPALLADATED SECONDARY BENZYLAMINE INCLUDING (SP(3))C-C(SP(3)) BOND ACTIVATION UNDER MILD CONDITIONS

Authors
DUNINA VV GOLOVAN EB
Citation
Vv. Dunina et Eb. Golovan, THE UNPRECEDENTED TRANSFORMATION OF A STERICALLY CROWDED CYCLOPALLADATED SECONDARY BENZYLAMINE INCLUDING (SP(3))C-C(SP(3)) BOND ACTIVATION UNDER MILD CONDITIONS, INORGANIC CHEMISTRY COMMUNICATIONS, 1(1), 1998, pp. 12-14
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS → ACNP
ISSN journal
13877003
Volume
1
Issue
1
Year of publication
1998
Pages
12 - 14
Database
ISI
SICI code
1387-7003(1998)1:1<12:TUTOAS>2.0.ZU;2-J
Abstract
An unusual process of palladium mediated cleavage of an (sp(3))C-C(sp( 3)) bond between two non-activated carbon atoms in a sterically crowde d secondary benzylamine is discovered. It includes the conversion of c yclopalladated N-methyl-alpha-tert-butplbenzylamine formed at the firs t stage into the ortho-palladated N-methylbenzylidenamine. (C) 1998 El sevier Science S.A.