SYNTHESIS OF ETA(1)-BUTADIENYL IRON COMPLEX UPON COUPLING OF 2 ORGANOMETALLIC ETA(1)-VINYL UNITS AND SELECTIVE DECOMPLEXATION AT ONE END

Authors
GUILLAUME V MAHIAS V LAPINTE C
Citation
V. Guillaume et al., SYNTHESIS OF ETA(1)-BUTADIENYL IRON COMPLEX UPON COUPLING OF 2 ORGANOMETALLIC ETA(1)-VINYL UNITS AND SELECTIVE DECOMPLEXATION AT ONE END, Journal of organometallic chemistry, 554(2), 1998, pp. 203-205
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
554
Issue
2
Year of publication
1998
Pages
203 - 205
Database
ISI
SICI code
0022-328X(1998)554:2<203:SOEICU>2.0.ZU;2-2
Abstract
The symmetric binuclear iron mu-bis(ethylidene) complex [Cp(dppe)Fe(= CHCH2CH2CH=)Fe(dppe)Cp][PF6](2) (2) reacts with the equivalent of two KOBut in THF to provide the mononuclear eta(1)-butadienyl complex Cp (dppe)Fe(CH=CH-CH=CH2) (4) isolated in 76% yield. (C) 1998 Elsevier Sc ience S.A. All rights reserved.