A NOVEL SERIES OF ASYMMETRIC TRINUCLEAR M(III) COMPLEXES (M = TI, V, CR, MN, FE, CO) WITH THE [M3O2](6+) CORE BY A DEOXIMATION REACTION EXEMPLIFIED BY THE V(III) COMPLEX
P. Chaudhuri et al., A NOVEL SERIES OF ASYMMETRIC TRINUCLEAR M(III) COMPLEXES (M = TI, V, CR, MN, FE, CO) WITH THE [M3O2](6+) CORE BY A DEOXIMATION REACTION EXEMPLIFIED BY THE V(III) COMPLEX, INORGANIC CHEMISTRY COMMUNICATIONS, 1(2), 1998, pp. 39-42
Compounds with the general formula [Et3NH] [M-3(III)(mu(3)-O) (Salox)(
2)(HSalox) (Salmp)], where M(III)=Ti, V, Cr, Mn, Fe or Co, H(2)Salox =
salicylaldoxime and H(3)Salmp = 2-(bis(salicylideneamino)methyl)pheno
l, have been synthesized by a deoximation reaction of salicylaldoxime.
(C) 1998 Elsevier Science S.A.