We present CCD spectra of 19 asteroids previously classified as D-type
covering the wavelength range 3500 less-than-or-equal-to lambda less-
than-or-equal-to 9600 angstrom. A comparison with previously published
photometric data shows excellent agreement. No small-scale absorption
features are seen, but two asteroids (102 Miriam and 914 Palisana) ex
hibit large-scale absorption (DELTAlambda approximately 2000angstrom)
characteristic of phyllosilicates and are confirmed as belonging to th
e C or P groups. A heliocentric colour gradient recently reported is p
resumed to be caused by the presence of silicates on asteroids lying w
ithin the main-belt, but it is unknown whether this material is inhere
nt to the asteroid or has been deposited there by impacts. We confirm
the existence of a reflectance slope - diameter correlation for D-type
asteroids previously suspected from studies of Trojan asteroids, with
smaller asteroids tending to be redder in colouration. The majority o
f D-type asteroids observed have a reflectance slope S' = 9.1%/10(3) a
ngstrom and albedo p(V) = 0.04, similar to that measured for comets P/
Halley and P/Neujmin 1, but rather different to comets such as P/Tempe
l 2 and P/Arend-Rigaux.