Ai. Gorshkov et al., INCLUSIONS OF NATIVE METALS AND OTHER MIN ERALS IN DIAMOND FROM KIMBERLITE PIPE-50, LIAONING, CHINA, Geohimia, (8), 1997, pp. 794-804
Inclusions in diamond from kimberlite Pipe 50, Liaoning Province, Chin
a, were detected using a complex of methods of analytical electron mic
roscopy. A close examination of these inclusions revealed the followin
g sequence in the crystallization of their phases. Syngenetic inclusio
ns of native metals (alpha-Fe, native Cr, and a metallic Cr-Fe-Ni phas
e), sulfides, and, possibly, apatite, graphite, and droplets of magnet
ite compose the oldest assemblage, which provides information on the h
igh-temperature and high-pressure environment, Florencite and Ce-fluor
ite affiliate with a younger assemblage of epigenetic minerals. The fl
aky magnetite and wuestite formed by the postcrystallization oxidation
of the native iron.