Df. Chen et al., HIGH-CONCENTRATION SUBSTITUTION OF GA AND AL IN R2FE17 (R = HO OR Y) - A NEUTRON STUDY OF CRYSTALLOGRAPHIC AND MAGNETIC-STRUCTURE, Physica. B, Condensed matter, 241, 1997, pp. 640-642
The crystallographic and magnetic structures of Ho2Fe9Ga8-xAlx (x = 0,
4) and Y2Fe9Ga8 were studied by powder neutron diffraction. The atomic
fractional occupancies of gallium and aluminum and the magnetic momen
ts of Ho and Fe atoms were obtained by Rietveld structure analysis met
hod. The gallium and aluminum occupy 18f, 18h and 6c sites, but prefer
to occupy the 6c and 18f sites (space group R (3) over bar m). The ma
gnetic moments of all the phases below the Curie temperature show unia
xial anisotropy. (C) 1998 Elsevier Science B.V. All rights reserved.