We have studied the influence of Mn concentration on the chemical and
magnetic order of the magnetic semiconductors Zn1-xMn2+xAs2 by neutron
powder diffraction. In Zn0.6Mn2.4As2 the mixed bilayer is strongly en
riched with Mn ions, and the antiferromagnetic structure is stabilized
at a much larger temperature range than in the stoichiometric compoun
d ZnMn2As2. (C) 1998 Elsevier Science B.V. All rights reserved.