Ab. Catalan et al., FABRICATION OF ON-CHIP BARIUM STRONTIUM-TITANATE CAPACITORS BY METALLOORGANIC DECOMPOSITION, Journal of materials research, 13(6), 1998, pp. 1548-1552
Metallo-organic thin film decomposition (MOD) was used in forming bari
um strontium titanate (BST) thin film capacitors on phosphorus doped p
olysilicon films deposited on 4 in. silicon wafers, A single step depo
sition process yielded highly uniform, crack-free BST films ranging up
to 0.25 mu m in thickness and having various step heights and dimensi
onal area. Scanning electron microscopy (SEM) showed very good step co
verage and planarization of the BST, The capacitors had capacitance de
nsities above 200 nF/cm(2), leakage current densities less than 1.55 m
u A/cm(2) at a bias voltage of 10 V, and a dielectric breakdown field
above 1 MV/cm, Small temperature coefficients of capacitance and dissi
pation (tan delta) were also observed, Frequency response measurements
were made using the BST capacitors and on-chip resistors in low pass
and high pass circuit configurations. A plot of relative gain and phas
e angle versus frequency showed excellent agreement with predicted res
ults.