INTERCALATION OF PYRIDINE AND ITS DERIVATIVES INTO CRYSTALLINE BISMUTH MOLYBDENUM HYDROUS OXIDE

Authors
SONG YJ ZHAO AM
Citation
Yj. Song et Am. Zhao, INTERCALATION OF PYRIDINE AND ITS DERIVATIVES INTO CRYSTALLINE BISMUTH MOLYBDENUM HYDROUS OXIDE, Journal of radioanalytical and nuclear chemistry, 231(1-2), 1998, pp. 17-20
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
231
Issue
1-2
Year of publication
1998
Pages
17 - 20
Database
ISI
SICI code
0236-5731(1998)231:1-2<17:IOPAID>2.0.ZU;2-5
Abstract
Bismuth molybdenum hydrous oxide was prepared by water-thermally direc t precipitation in relatively concentrated solutions. The composition of the resulting product was Bi2Mo3O12. 3.86H(2)O determined by therma l analysis and ICP. The X-ray powder diffraction patterns of the cryst al synthesized was identical with that of Bi2Mo3O12. 4.75H(2)O. Pyridi ne, 2,5-dimethylpyridine and 4-benzylpiridine were intercalated into i norganic crystal, significantly expanding interlayer distance along b axis in the monoclinic cell unit of bismuth molybdenum hydrous oxide. The organic molecules were intercalated by solvent exchange mechanism which mainly devoted to the expansion of interlayer spacing.