ISOTOPE EFFECTS IN TRITIUM EXCHANGE BETWEEN LIQUID PYRROLE, PYRROLIDINE AND GASEOUS-HYDROGEN

Authors
STOLARZ A SZYDLOWSKI J
Citation
A. Stolarz et J. Szydlowski, ISOTOPE EFFECTS IN TRITIUM EXCHANGE BETWEEN LIQUID PYRROLE, PYRROLIDINE AND GASEOUS-HYDROGEN, Journal of radioanalytical and nuclear chemistry, 231(1-2), 1998, pp. 107-111
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
Journal title
Journal of radioanalytical and nuclear chemistry → ACNP
ISSN journal
02365731
Volume
231
Issue
1-2
Year of publication
1998
Pages
107 - 111
Database
ISI
SICI code
0236-5731(1998)231:1-2<107:IEITEB>2.0.ZU;2-Z
Abstract
The overall tritium separation factor between molecular hydrogen and l iquid pyrrole and pyrrolidine has been measured between 280 and 325 K. The data are comparable with values of alpha measured for similar exc hange reactions involving ammonia and methylamine. There is a visible correlation of the isotope effect with the energy of hydrogen bond for med by NH groups of liquid ammonia, methylamine, pyrrole and pyrrolidi ne.