S. Fernandezvalverde et al., SYNTHESIS AND CHARACTERIZATION OF ANTIMONY MIXED-VALENCE COMPOUNDS INVIEW OF SOLID-STATE ISOTOPIC EXCHANGE STUDIES, Journal of radioanalytical and nuclear chemistry, 231(1-2), 1998, pp. 127-131
Several attempts have been made to synthesize mixed-valence compound o
f antimony at low temperature in view of studying the isotopic exchang
e in solids. The experimental procedure for the synthesis, at 263 K of
Cs-4((SbCl6)-Cl-III)((SbCl6)-Cl-v) has been established. This compoun
d seems very promising for isotopic exchange studies in the solid stat
e.