SYNTHESIS AND CHARACTERIZATION OF ANTIMONY MIXED-VALENCE COMPOUNDS INVIEW OF SOLID-STATE ISOTOPIC EXCHANGE STUDIES

Citation
S. Fernandezvalverde et al., SYNTHESIS AND CHARACTERIZATION OF ANTIMONY MIXED-VALENCE COMPOUNDS INVIEW OF SOLID-STATE ISOTOPIC EXCHANGE STUDIES, Journal of radioanalytical and nuclear chemistry, 231(1-2), 1998, pp. 127-131
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
ISSN journal
02365731
Volume
231
Issue
1-2
Year of publication
1998
Pages
127 - 131
Database
ISI
SICI code
0236-5731(1998)231:1-2<127:SACOAM>2.0.ZU;2-N
Abstract
Several attempts have been made to synthesize mixed-valence compound o f antimony at low temperature in view of studying the isotopic exchang e in solids. The experimental procedure for the synthesis, at 263 K of Cs-4((SbCl6)-Cl-III)((SbCl6)-Cl-v) has been established. This compoun d seems very promising for isotopic exchange studies in the solid stat e.