CATALYTIC BEHAVIOR IN SKELETAL ISOMERIZATION OF LINEAR BUTENES AND ACIDIC PROPERTIES OF AN I-PR2NH-TEMPLATED SAPO-11 MOLECULAR-SIEVE

Authors
TIAN HP SHI L YUAN JB BEKHEET ME LI CL
Citation
Hp. Tian et al., CATALYTIC BEHAVIOR IN SKELETAL ISOMERIZATION OF LINEAR BUTENES AND ACIDIC PROPERTIES OF AN I-PR2NH-TEMPLATED SAPO-11 MOLECULAR-SIEVE, Reaction kinetics and catalysis letters, 64(1), 1998, pp. 119-127
Citations number
35
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
64
Issue
1
Year of publication
1998
Pages
119 - 127
Database
ISI
SICI code
0133-1736(1998)64:1<119:CBISIO>2.0.ZU;2-O
Abstract
SAPO-11 samples were synthesized with i-Pr2NH as a novel template, and applied in catalytic skeletal isomerization of linear butenes. More l inear butenes were converted with increasing Si content in SAPO-11 sam ples, while the isa-butene selectivity was proportional to the Si cont ent only in the lower reaction temperature region. The maximum yield o f iso-butene was achieved around 763 K. The acidic properties of SAPO- 11 samples were studied by NH3-TPD and IR spectroscopy. The strong aci dity was due to the formation of Si domains in the framework lattice.