Vl. Kirillov et al., STABILITY AND ACTIVITY OF PD NANOPARTICLES ON SILICA AND ULTRADISPERSED DIAMOND, Reaction kinetics and catalysis letters, 64(1), 1998, pp. 169-175
In contrast to Pd/SiO2, Pd/diamond is extremely dispersed in the H-2 a
tmosphere up to 400 degrees C. Turnover number of Pd/diamond in benzen
e hydrogenation remains almost constant in a wide range of Pd particle
size (15-100 Angstrom) and is 5 times lower than that of Pd/SiO2.