TRANSFER OF ALK-1-ENYL GROUP FROM BORON TO BORON - PREPARATION OF B-[(E)-ALK-1-ENYL]-9-BORABICYCLO[3.3.1]NONANE

Authors
HOSHI M SHIRAKAWA K ARASE A
Citation
M. Hoshi et al., TRANSFER OF ALK-1-ENYL GROUP FROM BORON TO BORON - PREPARATION OF B-[(E)-ALK-1-ENYL]-9-BORABICYCLO[3.3.1]NONANE, Chemical communications, (11), 1998, pp. 1225-1226
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
11
Year of publication
1998
Pages
1225 - 1226
Database
ISI
SICI code
1359-7345(1998):11<1225:TOAGFB>2.0.ZU;2-P
Abstract
Treatment of (E)-alk-1-enyldicyclohexylborane 1 with B-methoxy-9-borab icyclo[3.3.1]nonane (B-MeO-9-BBN) at 0 degrees C results in transfer o f alk-1-enyl group from boron to boron to give B-[(E)-alk-1-enyl]-9-BB N 2 with retention of configuration.