Procedures which allow the measurement of scalars in premixed recircul
ating flames using digitally-compensated thermocouples or, alternative
ly, laser-Rayleigh scattering, are described together with the error s
ources associated with the use of these techniques. The procedure for
the numeric compensation of the thermocouple signals included experime
ntal data on the characteristics of the effect of velocity and tempera
ture on the time constant of the thermocouple and was optimised to gua
rantee the temporal resolution of the system. The Rayleigh system incl
uded its calibration in a propane/air flame and was optimised to avoid
contamination of Mie scattering from small particles. The effect of t
he photomultiplier shot noise on the Rayleigh signal is quantified and
used to compensate the results. The two techniques are shown to give
rise to results in close agreement and to be suitable to characterise
the turbulence nature of strongly recirculating premixed flames.