CHIRONS IN THE 1,3-DIOXANE SERIES - STEREOSPECIFIC CROSS-COUPLING REACTIONS AND CHIRALITY TRANSFERS

Authors
AMADJI M CAHARD D MORIGGI JD TOUPET L PLAQUEVENT JC
Citation
M. Amadji et al., CHIRONS IN THE 1,3-DIOXANE SERIES - STEREOSPECIFIC CROSS-COUPLING REACTIONS AND CHIRALITY TRANSFERS, Tetrahedron : asymmetry, 9(10), 1998, pp. 1657-1660
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
10
Year of publication
1998
Pages
1657 - 1660
Database
ISI
SICI code
0957-4166(1998)9:10<1657:CIT1S->2.0.ZU;2-E
Abstract
Palladium catalyzed cross-coupling reactions are described for enantio pure axially chiral vinylic bromides with arylzinc reagents leading to new compounds with axial chirality. In addition, transfers of axial t o central chirality are described. Both reactions exhibit full retenti on of enantiomeric purity. (C) 1998 Elsevier Science Ltd. All rights r eserved.