Harnessing solar energy by using photovoltaic cells has the potential
to become a major CO2-free energy source. Materials requirements for t
he solar cells based on four types of thin-film photovoltaics have bee
n estimated and compared with global reserves, resources and annual re
fining. The use of solar cells based on Cd, Ga, Ge, In, Ru, Se and Te
as a major energy-supply technology has severe resource constraints. O
ther systems such as a-Si without Ge and crystalline silicon do not in
volve such constraints. For some of these metals, there is the risk of
enhanced, environmentally deleterious concentrations in the ecosphere
due to leakage from manufacturing, use or waste handling. (C) 1998 El
sevier Science Ltd. All rights reserved.