SYNTHESIS OF TETRAALKYLTHIO-SUBSTITUTED PHTHALOCYANINES AND THEIR COMPLEXATION WITH AG(I) AND PD(II)

Authors
GUROL I AHSEN V BEKAROGLU O
Citation
I. Gurol et al., SYNTHESIS OF TETRAALKYLTHIO-SUBSTITUTED PHTHALOCYANINES AND THEIR COMPLEXATION WITH AG(I) AND PD(II), Journal of the Chemical Society. Dalton transactions, (4), 1994, pp. 497-500
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
4
Year of publication
1994
Pages
497 - 500
Database
ISI
SICI code
0300-9246(1994):4<497:SOTPAT>2.0.ZU;2-O
Abstract
The synthesis of new metal-free and nickel(II) phthalocyanines substit uted with four alkylthio groups SR (R = dodecyl or hexadecyl) is descr ibed. The new compounds have been characterized by elemental analyses, and IR, H-1 NMR and UV/VIS spectroscopy. The thio donors co-ordinate to Ag(I) and Pd(II) to give 2:1 metal-nickel phthalocyanine species. T he changes in the electronic spectra with respect to increasing concen tration of Pd(II) or Ag(I) have been investigated.