The new laser dye, perylene orange, doped into polycom glass (sol-gel
glass-poly(methyl methacrylate) composite) has been developed into a t
unable gain material with high performance. A sample polished to 0.02
mu m smoothness and lambda/5 flatness, over the central region, was ex
cited in an optical cavity with a second harmonic Q-switched Nd-doped
yttrium aluminium garnet laser as a pump source. The solid-state dye l
aser had a threshold of 53 mu J, a slope efficiency of 72% and a norma
lized photostability of 50 GJ mol(-1). The laser damage thresholds of
various host materials were obtained and the damage threshold of polyc
om glass was found to be 26 J cm(-2). The beam profile of a He-Ne lase
r transmitted through samples of host material showed that the optical
homogeneity of polycom glass is approaching that of pure polymers.