Rotational analyses have been carried out on eight thermically excited
emission bands of the infrared B-1 Pi --> X-1 Sigma(+) system of scan
dium monoiodide between 4000 to 5000 cm(-1), recorded by Fourier trans
form spectrometry. Rotational constants and energies are obtained for
X-1 Sigma(+) (v = 0, 1, 2) and B (1) Pi (v = 0-4) levels from which eq
uilibrium constants of the states are derived. Perturbational effects
are observed in the bands with v '' = 1 that are interpreted as conseq
uences of the avoided crossing of X-1 Sigma(+) (v = 1) and a(3) Delta(
1) (v = 0) at J = 70, A treatment of the perturbation is made using an
effective 2 x 2 matrix representation of the rotational energies of t
he two levels. (C) 1998 Academic Press.