C. Orsenigo et al., DYNAMIC INVESTIGATION OF THE ROLE OF THE SURFACE SULFATES IN NOX REDUCTION AND SO2 OXIDATION OVER V2O5-WO3 TIO2 CATALYSTS/, Industrial & engineering chemistry research, 37(6), 1998, pp. 2350-2359
Transient experiments performed over synthesized and commercial V2O5-W
O3/TiO2 catalysts during catalyst conditioning and during step changes
of the operating variables (SO2 inlet concentration and temperature)
show that conditioning of the catalyst is required to attain significa
nt and reproducible steady-state data in both the reduction of NOx and
the oxidation of SO2. The response time of conditioning for NOx reduc
tion is of a few hours and that for SO2 oxidation is of several hours.
Fourier transform infrared spectroscopy temperature programmed decomp
osition, and thermogravimetric measurements showed that catalyst condi
tioning is associated with a slow process of buildup of sulfates: the
different characteristic conditioning times observed in the reduction
of NOx and in the oxidation of SO2 suggest that the buildup of sulfate
s occurs first at the vanadyl sites and later on at the exposed titani
a surface. Formation of sulfates at or near the vanadyl sites increase
s the reactivity in the de-NOx reaction, possibly due to the increase
in the Bronsted and Lewis acidity of the catalyst, whereas the titania
surface acts as SO3 acceptor and affects the outlet SO3 concentration
during catalyst conditioning for the SO2 oxidation reaction. The resp
onse time to step changes in SO2 concentration and temperature is of a
few hours in the case of SO2 oxidation and much shorter in the case o
f NOx reduction. The different time responses associated with conditio
ning and with step changes in the settings of the operating variables
have been rationalized in terms of the different extent of perturbatio
n of the sulfate coverage experienced by the catalyst.