R. Hummeltenberg et al., A CONVENIENT ONE-POT SYNTHESIS OF STANNYLSILANES, Phosphorus, sulfur and silicon and the related elements, 123, 1997, pp. 255-261
Stannylsilanes were synthesized in high yields by reaction of organoti
nchlorides with organofluorosilanes and magnesium. The fluorosilanes w
ere prepared in good yields and under mild conditions by reaction of t
he corresponding chlorosilanes with [n-Bu4N][Ph3SnF2]. All products we
re characterized by Si-29, Sn-119 NMR spectroscopy and elemental analy
sis.