A CONVENIENT ONE-POT SYNTHESIS OF STANNYLSILANES

Citation
R. Hummeltenberg et al., A CONVENIENT ONE-POT SYNTHESIS OF STANNYLSILANES, Phosphorus, sulfur and silicon and the related elements, 123, 1997, pp. 255-261
Citations number
13
ISSN journal
10426507
Volume
123
Year of publication
1997
Pages
255 - 261
Database
ISI
SICI code
1042-6507(1997)123:<255:ACOSOS>2.0.ZU;2-C
Abstract
Stannylsilanes were synthesized in high yields by reaction of organoti nchlorides with organofluorosilanes and magnesium. The fluorosilanes w ere prepared in good yields and under mild conditions by reaction of t he corresponding chlorosilanes with [n-Bu4N][Ph3SnF2]. All products we re characterized by Si-29, Sn-119 NMR spectroscopy and elemental analy sis.