THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS-COMPOUNDS WITH SULFENATE ESTERS

Authors
HALL CD TWEEDY BR LOWTHER N
Citation
Cd. Hall et al., THE KINETICS AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS-COMPOUNDS WITH SULFENATE ESTERS, Phosphorus, sulfur and silicon and the related elements, 123, 1997, pp. 341-358
Citations number
32
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
123
Year of publication
1997
Pages
341 - 358
Database
ISI
SICI code
1042-6507(1997)123:<341:TKAMOT>2.0.ZU;2-4
Abstract
The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, ArnP(OCH2CF3)(3-n) with arylsulfenate esters, ArSOCH2CF3, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate th e two step mechanism involving arylthiophosphoranes as intermediates.