Lg. Dyachkov et Pm. Pankratov, ON THE USE OF THE SEMICLASSICAL APPROXIMATION FOR THE CALCULATION OF OSCILLATOR-STRENGTHS AND PHOTOIONIZATION CROSS-SECTIONS, Journal of physics. B, Atomic molecular and optical physics, 27(3), 1994, pp. 461-472
The semiclassical formula for the radial integrals of bound-bound dipo
le transitions derived in a previous paper is modified for obtaining m
ore accurate estimates and extending to bound-free transitions. The po
ssibility of these is due to the special definition of the mean value
of energy generalizing that of the previous paper. It is shown that th
e definition is optimal in the sense of the best agreement between sem
iclassical and exact quantum mechanical results in a limiting case. Ma
tching with the corresponding expression for free-free transitions is
also obtained. Good agreement with experiment and more accurate calcul
ations is found.