A new macroscopic test of spill tunneling in single-domain magnetic pa
rticles is proposed. It is shown that quantization of spin, even in pa
rticles of a considerable size, may lead to a detectable zero-field ma
ximum in the dependence of the rate of the magnetic relaxation on the
magnetic field. This effect must be especially pronounced in antiferro
magnetic particles. It is argued that recent observation by several gr
oups of the non-monotonic field dependence of the blocking temperature
in ferritin may, in fact, present the experimental evidence of this e
ffect. (C) 1998 Elsevier Science B.V. All rights reserved.