M. Romer et P. Lienemann, DETERIORATION OF SHOTCRETE IN THE SAFETY GALLERY OF THE GOTTHARD MOTORWAY TUNNEL BY SALT-CONTAINING WATER, Chimia, 52(5), 1998, pp. 197-201
The corrosion behavior of shotcrete in the safety gallery of the motor
way tunnel Gotthard was investigated. The tunnel was built in 1972/73,
sections with water-leading rocks show various signs of concrete degr
adation. Samples of corroded concrete were investigated in the laborat
ory for their chemical and mineralogical compositions. X-ray diffracti
on (XRD), X-ray fluorescence (XRF), and methods to determine acid-solu
ble silicon compounds and insoluble contents were used to characterize
the samples. Comparisons of original concrete with corroded samples s
how the existence or discrete interaction mechanisms. These mechanisms
lead either to harmless efflorescence, to detachments of concrete fro
m the rock or to more or less complete degradation of the cement paste
. Delamination or deterioration of concrete are related to the amount
and kind of transformation products formed due to action of specific i
onic species of the interacting water. Special attention is drawn to t
he formation of thaumasite, which may be formed under special conditio
ns, even when sulfate-resistant cements have been used. Physical and c
hemical properties of the cement paste as well as the composition of i
nteracting water are important for the service life of a concrete stru
cture. The potential of concrete degradation due to interaction with a
ggressive water may be lowered by preventing its contact or by drainin
g the water not to force it to penetrate the concrete structure.