P. Bague et al., EVIDENCE FOR THE PHENOMENON OF CARBURIZATION-DECARBURIZATION OF TUNGSTEN CARBIDE, Journal of physics. D, Applied physics, 27(2), 1994, pp. 402-406
Thoriated tungsten filaments acting as the main part of the cathode of
magnetrons used for creation of electromagnetic radiation in microwav
e ovens were partly carburized in order to limit, during the time of o
peration, the volatilization of thorium. The aim of this operation is
to create a layer of carbide at the surface of the filament, using a b
enzene source. The carburization of tungsten being a reversible chemic
al reaction at high temperature, it is quite possible to carry out car
burization-decarburization cycles. The interest of this work is to stu
dy some parameters leading to the decarburization of partly carburized
filaments in order to avoid this phenomenon during fabrication and no
rmal use of magnetrons.