J. Ramirezcastellanos et al., MICROSTRUCTURAL CHARACTERIZATION OF GASR2CA2CU3O9-1CUNO2N+3(DELTA, N=3 MEMBER OF THE HOMOLOGOUS SERIES OF SUPERCONDUCTORS GASR2CAN), Physica. C, Superconductivity, 251(3-4), 1995, pp. 279-284
The microstructure of the n = 3 member of the homologous series of sup
erconductors GaSr2Can-1CunO2n+3 prepared under high pressure (6 GPa) w
as investigated by means of selected-area electron diffraction (SAED)
and high-resolution transmission electron microscopy (HRTEM). The GaSr
2Ca2Cu3O9+delta phase has an orthorhombic structure with a double peri
odicity along the b-axis, due to the intralayer ordering between two d
ifferent types of GaO4 chains. Also, interlayer disordering of the cha
ins along the c-axis was observed.