TRANS-METHYL-AZIDO-BIS(TRIISOPROPYLPHOSPI N)PLATIN(II), [PTN3(CH3)((PPR3)-PR-I)(2)]

Authors
SCHLECHT S FAZA N MASSA W DAPPRICH S FRENKING G DEHNICKE K
Citation
S. Schlecht et al., TRANS-METHYL-AZIDO-BIS(TRIISOPROPYLPHOSPI N)PLATIN(II), [PTN3(CH3)((PPR3)-PR-I)(2)], Zeitschrift fur anorganische und allgemeine Chemie, 624(6), 1998, pp. 1011-1014
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
624
Issue
6
Year of publication
1998
Pages
1011 - 1014
Database
ISI
SICI code
0044-2313(1998)624:6<1011:TN[>2.0.ZU;2-T
Abstract
[PtN3(CH3)((PPr3)-Pr-i)(2)] has been prepared by reductive elimination of ethane from [Pt(CH3)(3)N-3](4) in the presence of triisopropylphos phine at 80 degrees C. The complex is characterized by IR and NMR spec troscopy and by crystal structure determination, as well as by ab init io calculations. [PtN3(CH3)((PPr3)-Pr-i)(2)], which is in trans-config uration here, crystallizes in the monoclinic space group P2(1), Z = 2, and with the lattice dimensions a=806.9(1), b=1384.3(1), c = 1093.8(1 ) pm, beta= 94.107(10)degrees.