Modulated adiabatic passage on oriented nuclei (MAPON) is a technique
developed specifically to measure very small electric quadrupole inter
actions (EQIs) at radioactive probe nuclei even when such interactions
are masked in the frequency domain by inhomogeneous magnetic broadeni
ng associated with a dominant magnetic hyperfine interaction. In this
paper an overview of the technique is presented with particular refere
nce to (CoCo)-Co-60 EQI measurements which were an important step in e
stablishing MAPON methodology. MAPON results for dilute nd impurities
in ferromagnetic Fe and Ni metal hosts are reviewed including presenta
tion of new data for (CoNi)-Co-58 and (CoNi)-Co-60. Priorities for fut
ure studies are provided on the basis of this review.