DETERMINATION OF OXYGEN IN ORGANOSILICON POLYMERS AND ORGANIC MATERIALS BY INERT-GAS FUSION WITH A PLATINUM-CARBON CONVERTER

Organosilicon polymers have attracted considerable attention as a new class of functional polymers of the next generation because of their u nique electronic and optical properties originating from the delocaliz ation of sigma-sigma conjugated electrons along the Si-Si main chain of polysilane. Thus, for these polymers, oxygen is the most remarkable impurity. Nevertheless, the determination of oxygen in any organic ma terial is extremely difficult. Especially, for oraganosilicon compound s, conventional methods do not give good results. In this study we inv estigated the reason for the low recoveries of organosilicon compounds by several kinds of determination methods, and developed a new determ ination method involving on inert-gas fusion equipped converter, which includes platinum-carbon. According to our method, oxygen in organosi licon polymers can be determined quantitatively. We confirmed that our new method is applicable not only to organosilicon materials, but als o to organic and organometallic compounds as well as inorganic materia ls.