Ni-Mn alloys were electrodeposited on stainless steel substrates from
simple sulphate baths with ammonium sulphate as the additive. The infl
uence of Ni/Mn metal ratio (in the bath) on microstructure of the coat
ings was investigated with colour polarisation optical microscopy. The
most homogenous and textured deposit was obtained with a Ni/Mn metal
ratio of 0.67. Ni/Mn metal ratio of above 6.0 introduced surface rough
ness in the coating. Multiphase deposits were obtained with a Ni/Mn me
tal ratio in the range 1.0 to 3.0. Monophase deposits could be plated
only from baths with a Ni/Mn metal ratio of 0.67 to 0.93. In three cas
es, unique microstructures were observed.