A SHORT ROUTE TO ALPHA-CHLORO-ULSONIC AND ALPHA-AZIDO-ULOSONIC ESTERS

Authors
LAKHRISSI M CHAPLEUR Y
Citation
M. Lakhrissi et Y. Chapleur, A SHORT ROUTE TO ALPHA-CHLORO-ULSONIC AND ALPHA-AZIDO-ULOSONIC ESTERS, Tetrahedron letters, 39(26), 1998, pp. 4659-4662
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
26
Year of publication
1998
Pages
4659 - 4662
Database
ISI
SICI code
0040-4039(1998)39:26<4659:ASRTAA>2.0.ZU;2-A
Abstract
A two step route to alpha-chloro-ulosonic eaters from lactones involvi ng the reaction of dichloroolefins with m-chloroperbenzoic acid in dic hloromethane is described. Subsequent substitution of chlorine by the azide ion yields the corresponding anomeric azido-esters, which may be useful intermediates for the preparation of ''anomeric amino-acids'' and related compounds. (C) 1998 Elsevier Science Ltd. All rights reser ved.