V. Kondratovich et Jb. Delos, SCALED-ENERGY FLOQUET SPECTROSCOPY IN A STRONG ELECTRIC-FIELD - A SEMIQUANTAL CALCULATION OF THE RECURRENCE SPECTRUM, Physical review. A, 57(6), 1998, pp. 4604-4615
We consider a hydrogen atom in a strong static electric field with a w
eak parallel radio-frequency (rf) field. We compute the photoabsorptio
n spectrum by calculating the spectrum of Floquet states, including th
eir quasienergies and their oscillator strengths. Our calculation is b
ased upon ''semiquantal'' formulas: we calculate the discrete spectrum
of quasienergy states by using a quantum adiabatic approximation comb
ined with semiclassical (Bohr-Sommerfeld) quantization rules. We expre
ss this spectrum in a manner consistent with the method of scaled-vari
able spectroscopy, and then calculate the Fourier transform. These cal
culated absorption spectra and recurrence spectra are in good agreemen
t with experiments on Li atoms. Additional approximations show that th
e recurrence spectrum is approximately equal to the product of the rec
urrence spectrum in a static field times an envelope function. That en
velope function is the Fourier transform of a cluster of sidebands sur
rounding a progenitor level in the rf field. The resulting formula agr
ees with the low-frequency limit of a formula obtained from a semiclas
sical treatment.