SYNTHESIS, STRUCTURE AND PROPERTIES OF NEW PYRIDYLAMINOPHOSPHINE COMPLEXES

Authors
AUCOTT SM SLAWIN AMZ WOOLLINS JD
Citation
Sm. Aucott et al., SYNTHESIS, STRUCTURE AND PROPERTIES OF NEW PYRIDYLAMINOPHOSPHINE COMPLEXES, Phosphorus, sulfur and silicon and the related elements, 125, 1997, pp. 473-476
Citations number
4
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
125
Year of publication
1997
Pages
473 - 476
Database
ISI
SICI code
1042-6507(1997)125:<473:SSAPON>2.0.ZU;2-9
Abstract
Reaction of diphenylphosphino-2-aminopyridine with a variety of late t ransition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in m ost cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election deloca lisation over the P-N bond.