PREPARATION AND STRUCTURAL STUDIES OF [MO(N3S2)(R-2(O)PNP(S)R-2)(2)]

Authors
LY TQ MABBS F MCINNES E SLAWIN AMZ WOOLLINS JD
Citation
Tq. Ly et al., PREPARATION AND STRUCTURAL STUDIES OF [MO(N3S2)(R-2(O)PNP(S)R-2)(2)], Phosphorus, sulfur and silicon and the related elements, 125, 1997, pp. 497-500
Citations number
5
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
125
Year of publication
1997
Pages
497 - 500
Database
ISI
SICI code
1042-6507(1997)125:<497:PASSO[>2.0.ZU;2-O
Abstract
The compounds [Mo(N3S2){Ph-2(O)PNP(S)Ph-2}(2)] 1 [Mo(N3S2){Pr-1(2)(O)P NP(S)Pr-1(2)}(2)] 2 have been synthesised by treating [MoCl3(N3S2)] Wi th KN(PPh2S)(2) or KN((PPh2S)-Ph-1)(2). X-Ray structures of 1 and 2 ha ve been solved. On complexation, the MoN3S2 ring remained planar, but the Mo(OPNPS)(2) rings are puckered.